Download Advances in Cycloaddition. Volume 5 by M. Harmata PDF

By M. Harmata

The improvement and alertness of cycloaddition method is still on the vanguard of analysis in artificial natural chemistry. This quantity starts with a evaluation of tools to be had for the synthesis of 7-membered jewelry and is with paintings on metal-catalyzed cycloadditions. there's then an replace at the cycloaddition chemistry of 2-pyrone, after which a special program of photocycloaddition is specific. the ultimate bankruptcy is a dialogue of the most recent explorations of the response of rhodium-stabilized vinyl carbenoids with dienes.

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4+2] Cycloadditions of 2-Pyrones with Alkenes . . . . A. Aromatic Products . . . . . . . . . . . B. D i h y d r o b e n z e n e Products . . . . . . . . . C. D o u b l e D i e l s - A l d e r Cycloadditions . . . . . . D. Isolable Bicycloadducts . . . . . . . . . . Conclusions . . . . . . . . . . . . . . Acknowledgments . . . . . . . . . . . . References . . . . . . . . . . . . . . 50 52 52 54 54 56 80 80 80 Advances in Cycloaddition Volume 5, pages 47-83.

50 52 52 54 54 56 80 80 80 Advances in Cycloaddition Volume 5, pages 47-83. Copyright 9 1999 by JAI Press Inc. All rights of reproduction in any form reserved. ISBN: 0-7623-0346-8 47 48 BENJAMIN T. WOODARD and GARY H. POSNER ABSTRACT This review of recent progress in [4+2] cycloaddition of 2-pyrone dienes emphasizes control of relative and absolute stereochemistry. Discussion includes the development of mild reaction conditions and electronic matching of reaction partners, allowing the isolation of bicyclic lactones with control of relative stereochemistry.

Rev. 1997, 97, 523-596. ; Tam, W. Chem. Rev. 1996, 96, 49. 44 PAUL A. WENDER and JENNIFER A. LOVE 80. ; Natchus, M. ; Shuker, A. J. In TAXOL Science and Applications: M. ; CRC Press: New York, 1995, pp. 123-187. 81. Wender, P. ; Ihle, N. C. J. Am. Chem. Soc. 1986, 108, 4678. 82. Wender, P. ; Snapper, M. L. Tetrahedron Lett. 1987, 28, 2221. 83. Wender, P. ; Nuss, J. ; Smith, D. ; Bordner, J. J. Org. Chem. 1997, 62, 4908. 84. Wender, P. ; Correia, C. R. ; Ihle, N. C. J. Am. Chem. Soc. 1988,110, 5904.

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